Study of the shielding properties of polyvinyl butyral films filled with carbon nanomaterials

Keywords: polymer composite, microwave radiation, shielding, carbon nanomaterials.

Abstract

The ubiquity of sources of ultrahigh frequency radiation poses a potential threat to biological objects and the operation of sensitive electronics. In this regard, the development of effective protection measures is an urgent task. In this work, thin films based on polyvinyl butyral were obtained with fillings in the form of single-walled (SWCNTs) and multi-walled nanotubes (MWCNTs), reduced graphene oxide and carbon black of various grades. The morphology of the surface was studied using a scanning electron microscope. This shows the general patterns in the distribution of carbon nanomaterials in the polymer matrix. The absorption, transmission, and reflection coefficients of electromagnetic waves in the microwave range were also obtained. It is shown that films with the addition of SWCNTs exhibit high wave reflection coefficients and are reflective screens. The work done has demonstrated the prospects for further study of flexible absorbent coatings based on polymer composite materials.

References

Soares, B. G., Barra, G. M., & Indrusiak, T. (2021). Conducting polymeric composites based on intrinsically conducting polymers as electromagnetic interference shielding/microwave absorbing materials‒A review. Journal of Composites Science, 5(7), 173. https://doi.org/10.3390/jcs5070173.

Shiyanova, K. A., Gudkov, M. V., Gorenberg, A. Y., Rabchinskii, M. K., Smirnov, D. A., Shapetina, M. A., ... & Melnikov, V. P. (2020). Segregated network polymer composites with high electrical conductivity and well mechanical properties based on PVC, P (VDF-TFE), UHMWPE, and rGO. ACS omega, 5(39), 25148‒25155. https://doi.org/10.3892/ijmm.2016.2777.

Goldade, V., Shapovalov, V., Zotov, S., Vinidiktova, N., Zhu, S., & Zhu, Y. (2024). Radar-absorbing materials based on polymer composites. Polymer Materials and Technologies, 10(1), 6–2. http://doi.org/10.32864/polymmattech-2024-10-1-6-25. (in Russ.).

Vazquez, E., & Prato, M. (2009). Carbon nanotubes and microwaves: interactions, responses, and applications. Acs nano, 3(12), 3819‒3824. https://doi.org/10.1021/nn901604j.

Martin, C. A., Sandler, J. K. W., Windle, A. H., Schwarz, M. K., Bauhofer, W., Schulte, K., & Shaffer, M. S. P. (2005). Electric field-induced aligned multi-wall carbon nanotube networks in epoxy composites. Polymer, 46(3), 877‒886. https://doi.org/10.1016/j.polymer.2004.11.081.

Minakov, G., Shirokih, S., Kornilov, D., & Koroleva, M. (2022). Porous polymer nanocomposite materials for environmental protection. Chemistry for Sustainable Development, 30, 56‒67. https://doi.org/10.15372/CSD2022358.

Meng, F., Wang, H., Huang, F., Guo, Y., Wang, Z., Hui, D., & Zhou, Z. (2018). Graphene-based microwave absorbing composites: A review and prospective. Composites Part B: Engineering, 137, 260‒277. https://doi.org/10.1016/j.compositesb.2017.11.023.

Abdalla, I., Yu, J., Li, Z., & Ding, B. (2018). Nanofibrous membrane constructed magnetic materials for high-efficiency electromagnetic wave absorption. Composites Part B: Engineering, 155, 397‒404. https://doi.org/10.1016/j.compositesb.2018.09.026.

Abdalla, I., Cai, J., Lu, W., Yu, J., Li, Z., & Ding, B. (2023). Recent progress on electromagnetic wave absorption materials enabled by electrospun carbon nanofibers. Carbon, 213, 118300. https://doi.org/10.1016/j.carbon.2023.118300.

Abbas, S. M., Chandra, M., Verma, A., Chatterjee, R., & Goel, T. C. (2006). Complex permittivity and microwave absorption properties of a composite dielectric absorber. Composites Part A: applied science and manufacturing, 37(11), 2148‒2154. https://doi.org/10.1016/j.compositesa.2005.11.006.

Kolanowska, A., Janas, D., Herman, A. P., Jędrysiak, R. G., Giżewski, T., & Boncel, S. (2018). From blackness to invisibility–Carbon nanotubes role in the attenuation of and shielding from radio waves for stealth technology. Carbon, 126, 31–52. https://doi.org/10.1016/j.carbon.2017.09.078.

Zeng, X., Cheng, X., Yu, R., & Stucky, G. D. (2020). Electromagnetic microwave absorption theory and recent achievements in microwave absorbers. Carbon, 168, 606–623. https://doi.org/10.1016/j.carbon.2020.07.028.

Shiyanova, K. A., Gudkov, M. V., Gorenberg, A. Y., Rabchinskii, M. K., Smirnov, D. A., Shapetina, M. A., ... & Melnikov, V. P. (2020). Segregated network polymer composites with high electrical conductivity and well mechanical properties based on PVC, P (VDF-TFE), UHMWPE, and rGO. ACS omega, 5(39), 25148‒25155. https://doi.org/10.1021/acsomega.0c02859.

Brekhovskikh, L. (2012). Waves in layered media (Vol. 16). Elsevier.

Published
2025-12-15
How to Cite
Kozhevnikov, I. A., Torkunov, M. K., Chmutin, I. A., Melnikov, V. P., & Shiyanova, K. A. (2025). Study of the shielding properties of polyvinyl butyral films filled with carbon nanomaterials. Chemical Safety Science, 9(2), 228‒239. https://doi.org/10.25514/CHS.2025.2.29015
Section
Protective methods and materials