Oxygen absorption by alcohol-aqueous solutions of the ternary styrene epoxide – hydroquinone – pyridine system
Abstract
Epoxides are known as important intermediates in the biotransformation of aromatic and olefinic substances, which catalytically are consumed in the presence of acids and transition metal salts. The absorption of oxygen in the reactor of a manometric installation by the ternary system styrene epoxide – hydroquinone – pyridine (SE – HQ – Py) was discovered and kinetically studied. The oxidation rate in aqueous tert-butanol at a volume ratio of t-BuOH : H2O = 4 : 1 is approximated by the expression V = k [SE]1[Py]1[HQ]0.3. The value of the effective activation energy, calculated from the temperature dependence of the initial oxidation rate, Ea = 36 ± 3.0 kJ/mol. A study of the consumption of the components of the ternary system using high-performance liquid chromatography, as opposed to SE and HQ, showed that pyridine is not consumed during oxidation. These data indicate a catalytic mechanism of pyridine action in the ternary system.
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