Photo-Fenton degradation of methyl orange using heterogeneous catalysts based on polyphenylferrosiloxane
Abstract
The study is performed in line with a currently topical trend of using Advanced Oxidation Processes (AOPs) for degradation of organic pollutants in wastewater. Samples of polyphenylsiloxane and composites on the basis of biogenic silica obtained from rice husk, and polyphenylsiloxane with different component ratios have been synthesized. The presence of functional groups on the surface of composites is studied by IR spectroscopy. The catalytic activity of the obtained samples in the degradation reaction of methyl orange (pH = 6.8) under UV irradiation and in the presence of hydrogen peroxide has been studied. It is shown that the composite with the 1 : 1 ratio of polyferrophenylsiloxane to silicon dioxide is characterized by high catalytic activity and stable functioning in the degradation reaction of methyl orange under experimental conditions. The obtained material can be used as an inexpensive and eco-friendly Fenton-like catalyst for efficient removal of persistent organic pollutants from wastewater.
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Copyright (c) 2020 Olga D. Arefieva, Maria A. Samus’, Alexandra I. Pisartseva, Svetlana G. Krasitskaya, Marina S. Vasylieva and Nina V. Maslova
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