Сравнительная оценка состава и свойств соединений родия и платины с P(III)-производными каликс[4]резорцинов
Аннотация
Проведена сравнительная оценка влияния исходных соединений – производных каликс[4]резорцинов, содержащих функциональные группы по нижнему ободу молекулы (арилдифенилфосфины либо арилтрифенилфосфониобромиды или арилдиэтиламинодифенилфосфониобромиды), растворителей (ацетон, этанол) и соединений металлов {RhCl3∙nH2O, [Rh2(AcO)4 2H2O], PtCl4}на состав и строение супрамолекулярных комплексов. Установленные закономерности по совместному влиянию органических сред, соединений металлов, P(III)-производных каликс[4]резорцинов на образование продуктов и наблюдаемая зависимость между функциональными свойствами супрамолекулярных комплексов и их составом и строением открывают новые возможности для получения соединений с заранее программируемыми свойствами.
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