Особенности очистки дициклогексил-18-краун-6 через получение кристаллических стехиометрических комплексов с  HN-кислотными органическими молекулами

В.Н. Глушко; Н.Ю. Садовская; Л.И. Блохина; С.К. Белусь; В.М. Ретивов; М.Ю. Жила

doi:10.25514/CHS.2021.2.20002

В.Н. Глушко Федеральное государственное унитарное предприятие «Институт химических реактивов и особо чистых химических веществ Национального исследовательского центра «Курчатовский институт», Москва, Россия https://orcid.org/0000-0001-6641-8715
Н.Ю. Садовская Российский химико-технологический университет им. Д.И. Менделеева, Москва, Россия https://orcid.org/0000-0002-5716-5880
Л.И. Блохина Федеральное государственное унитарное предприятие «Институт химических реактивов и особо чистых химических веществ Национального исследовательского центра «Курчатовский институт», Москва, Россия https://orcid.org/0000-0001-9629-4645
С.К. Белусь Федеральное государственное унитарное предприятие «Институт химических реактивов и особо чистых химических веществ Национального исследовательского центра «Курчатовский институт», Москва, Россия https://orcid.org/0000-0002-4676-1070
В.М. Ретивов Федеральное государственное унитарное предприятие «Институт химических реактивов и особо чистых химических веществ Национального исследовательского центра «Курчатовский институт», Москва, Россия https://orcid.org/0000-0002-3649-2778
М.Ю. Жила Федеральное государственное унитарное предприятие «Государственный научный центр «НИОПИК», Московская область, Россия https://orcid.org/0000-0001-9828-2904

DOI: https://doi.org/10.25514/CHS.2021.2.20002

Ключевые слова: краун-эфиры, комплексообразование, изомеры, гидрирование

Аннотация

Представлена технологичная методика синтеза и очистки дициклогексил-18-краун-6 (ДЦГ18К6) методом жидкофазного каталитического гидрирования ДБ18К6 на рутениевом катализаторе в 50% изопропаноле при повышенном давлении и температуре. Предложен эффективный способ выделения смеси изомеров А и В ДЦГ18К6 и их разделения. Перспективным является применение ДБ18К6, как компонента в различных композитах для эффективного удаления Sr²⁺ в средах с высокой кислотностью.

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