Валидация способа определения хлорорганических пестицидов в зерне и муке методом хромато-масс-спектрометрии с использованием пробоподготовки QuEChERS
Аннотация
Валидирован способ определения 9 хлорорганических пестицидов (a-ГХЦГ, β-ГХЦГ, γ-ГХЦГ, ДДЕ, ДДД, ДДТ, альдрин, гептахлор, гексахлорбензол) в зерне и муке c использованием метода газовой хромато-масс-спектрометрии. Выбраны оптимальные условия хроматографирования и пробоподготовки, основанной на методе QuEChERS. Степень извлечения пестицидов составила от 88 до 119%. Диапазон определяемых концентраций пестицидов составил 0,002 – 0,020 мг/кг. Относительное стандартное отклонение результатов анализа не превысило 16,0%. Значения LOD (предел обнаружения) составили 0,0003 – 0,0011 мг/кг, LOQ (предел количественного определения) – 0,0011 –0,0034 мг/кг.
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