Сравнительная оценка состава и свойств соединений родия с супрамолекулами
Аннотация
Представлены результаты исследований по сравнительной оценке влияния супрамолекул ‒ каликс[4]резорцинов и дибензо-18-краун-6, функционализированных различными фрагментами (гидроксиэтокси-, фосфорил-, амино-, нитрогруппами) на состав продуктов, которые образуются при их взаимодействии с акватрихлоридом родия (III) и диакватетраацетатом диродия (II) в органических средах. Установлено, что выделение и состав продуктов определяется свойствами органической среды. Показана взаимосвязь между исследованными функциональными свойствами комплексных соединений, такими как каталитическая, бактерицидная и антиоксидантная активность, и их составом и строением. Исследованные закономерности влияния растворителей на выделение термодинамически стабильных продуктов в твердую фазу в виде супрамолекулярных комплексов родия разнообразного состава и строения открывает широкие перспективы для управления процессами минимизации потерь родия в отходах химической промышленности, связанной с соединениями, участвующими в катализе и проводимых в неводных органических средах.
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