Гибридный фотокатализатор нано-диоксид титана/диатомит для удаления токсичных органических загрязнителей из воды с помощью эффективных окислительных процессов (АОPs)
Аннотация
В статье представлены результаты изучения фотокаталитической активности гибридной каталитической системы диатомит/диоксид титана, представляющей собой композит на основе наноразмерного диоксида титана, привитого на поверхность диатомита, которая была применена для разложения фенола в водном растворе под действием УФ излучения, как пример эффективных окислительных процессов типа AOPs (Advanced Oxidation Processes). Катализатор был синтезирован методом модифицированного гетерогенного гидролиза в присутствии диатомита с использованием четыреххлористого титана в качестве прекурсора диоксида титана. Фотокатализатор показал высокую активность в разложении фенола в водном растворе: так, степень деградации фенола достигала 90% в течение 180 мин процесса в зависимости от исходной концентрации загрязняющего вещества. Кинетика процесса фоторазложения хорошо описывается моделью адсорбции Ленгмюра-Хиншельвуда. Полученный композитный катализатор при дозе 2 г/л и исходном содержании фенола 10 г/л удаляет загрязнитель из водного раствора, достигая значений ПДК по фенолу в сточных водах (~5 мг/л) в течение 54 мин фотокатализа.
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